An octahedral complex of M^{+3} with NH_3 and | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) The complex has the formula $[M(NH_3)_4(NO_2)_2]^+$. Since there are two $NO_2^-$ ligands,they can be arranged in $cis$ or $trans$ positions,which

Vedclass · Accepted Answer

Both $(a)$ and $(b)$

Vedclass · Answer

(D) The complex has the formula $[M(NH_3)_4(NO_2)_2]^+$. Since there are two $NO_2^-$ ligands,they can be arranged in $cis$ or $trans$ positions,which leads to geometrical isomerism. Additionally,the $NO_2^-$ ligand is an ambidentate ligand,meaning it can coordinate through either the $N$ atom or the $O$ atom. Since the complex contains both $M-N$ and $M-O$ linkages,it exhibits linkage isomerism. Therefore,the complex shows both geometrical and linkage isomerism.

An octahedral complex of $M^{+3}$ with $NH_3$ and $NO_2^{-}$ ligands has four $M-N$ linkages and two $M-O$ linkages. Which type of isomerism will such a complex exhibit?

Similar Questions

Amongst $[Ni(H_{2}O)_{6}]^{2+}$, $[Ni(PPh_{3})_{2}Cl_{2}]$, $[Ni(CO)_{4}]$ and $[Ni(CN)_{4}]^{2-}$, the paramagnetic species are

Which of the following complexes exhibit geometrical isomerism?
$I$) $[Co(en)(NH_3)_2 Cl_2] Cl$
$II$) $[Co(NH_3)_4 Cl_2] Cl$
$III$) $[Co(en)_3] Cl_3$
$IV$) $[Co(en)_2 Cl_2] Br$

Which of the following statements is correct?

How many isomers are possible for the complex ion $[Cr(NH_3)(OH)_2Cl_3]^{2-}$?

The number of optical isomers exhibited by the iron complex $(A)$ obtained from the following reaction is $.........$
$FeCl_3 + KOH + H_2C_2O_4 \rightarrow A$

Vedclass Test Series

Exam Paper Generator

Online Exam Module